A Lewis formula consists of two C–H sigma bonds, a C–O sigmabond, a C=O pi bond and two non-bonding electron pairs. Because of overlap mixing, the molecular orbitals are not as localized as the Lewis structure suggests. The lowest energy M.O (#1) is essentially the C–O sigma bond. The next two orbitals (#2 & 3) are primarily the C–H sigma bonds. Orbital #4 is occupied by one of the non-bonding pairs, chiefly in an sp hybrid region on oxygen. Orbital #5 is the π-bonding orbital, leaving orbital #6 for the remaining non-bonding pair. Unlike #4, this electron pair occupies an oxygen p-orbital. Antibonding orbital #7 is clearly the π* orbital.
The molecules and their orbitals may be rotated by clicking on the structure and dragging the mouse. Holding the shift key during this operation allows zooming.